Nimonic 90 (UNS N07090 / W.Nr. 2.4632) and Nimonic 80A (UNS N07080 / W.Nr. 2.4631 / often just called Nimonic 80 or Nimonic 80A) are both γ′-precipitation hardened Ni–Cr–Co–Ti–Al superalloys originally developed by Henry Wiggin (UK) for 650–870°C creep-resistant turbine components. They share the same base strengthening mechanism — coherent γ′ [Ni₃(Al,Ti)] precipitation — but differ in cobalt content, titanium/aluminum ratio, allowable stress-rupture capability, and typical product form emphasis.
This article provides a rigorous side-by-side comparison to guide alloy selection between these two classic Nimonic grades.
1. Nominal Chemistry Comparison
|
Element (wt%) |
Nimonic 80A (N07080 / 2.4631) |
Nimonic 90 (N07090 / 2.4632) |
Functional Difference |
|---|---|---|---|
|
Ni |
Bal. (~72–76 in old refs; actually ~57–62) |
Bal. (~55–60) |
— |
|
Cr |
18.0–21.0 (typ 19.5) |
18.0–21.0 (typ 19.5) |
Both form Cr₂O₃; Nimonic 90 same Cr level |
|
Co |
≤ 2.0 (max, often 1.0 typ) |
15.0–21.0 (typ 18.0) |
★ Key diff: Co in 90 raises γ′ solvus (~985–1010°C vs ~950°C for 80A) → better high-T creep |
|
Ti |
2.0–2.7 (typ 2.4) |
2.2–3.0 (typ 2.6) |
Both main γ′ former; 90 slightly higher range |
|
Al |
1.0–1.8 (typ 1.4) |
1.0–2.0 (typ 1.5) |
Similar; 90 can go to 2.0 max |
|
(Al+Ti) total |
≈ 3.4–4.2 % |
≈ 3.8–4.8 % |
90: marginally higher → slightly more γ′ pot. |
|
C |
0.04–0.10 |
0.04–0.10 |
Grain-boundary carbide control |
|
Fe |
≤ 3.0 (typ ≤1.0) |
≤ 3.0 (typ ≤1.0) |
Impurity |
|
B / Zr |
≤ 0.008 / ≤ 0.06 (optional) |
≤ 0.015 / ≤ 0.05 (optional) |
Grain-boundary strengtheners |
Key takeaway: The presence of 15–18% Co in Nimonic 90 is the principal metallurgical differentiator — it retards γ′ coarsening, elevates γ′ solvus, and improves creep-rupture strength particularly at 750–870°C. Nimonic 80A is essentially Co-free (< 2%).
2. Heat Treatment & Aging Practice
|
Item |
Nimonic 80A (N07080) |
Nimonic 90 (N07090) |
|---|---|---|
|
Solution Anneal (SA) |
1050–1080°C × soak → oil/water quench (lower than 90 due to lower γ′ solvus) |
1080–1150°C (typ 1120–1140°C) × soak → oil/water quench |
|
Aging (Precipitation) |
Typically single-stage or mild double: 700°C × 16 h / AC (some specs add 650°C × 8–16 h) |
Double-stage standard (BS HR 1): 700–750°C × 16 h / AC + 650°C × 16 h / AC |
|
γ′ Solvus |
≈ 950–970°C |
≈ 985–1010°C |
|
Over-aging Risk |
η (Ni₃Ti) forms > 950°C; earlier than 90 |
η forms > 975–1000°C extended hold |
→ Both require solution quench + aging; Nimonic 90's higher solution and double-aging are tuned for max. stress-rupture. Nimonic 80A sometimes used with single-stage 700°C aging in less critical apps.
3. Typical Mechanical Properties (Aged Condition)
Room Temperature (Aged):
|
Property |
Nimonic 80A (N07080) |
Nimonic 90 (N07090) |
|---|---|---|
|
Rm |
1080–1200 MPa |
1150–1280 MPa |
|
Rp0.2 |
650–800 MPa |
750–900 MPa |
|
A₅₀ |
15–25 % |
15–25 % |
|
Hardness |
32–40 HRC |
34–42 HRC |
Elevated-Temperature Tensile (Aged — Typical):
|
T(°C) |
Nimonic 80A Rm/Rp0.2 (MPa) |
Nimonic 90 Rm/Rp0.2 (MPa) |
|---|---|---|
|
20 |
1120–1180 / 700–780 |
1180–1260 / 800–870 |
|
650 |
900–970 / 560–630 |
950–1020 / 620–690 |
|
760 |
720–790 / 450–510 |
780–850 / 500–570 |
|
815 |
560–630 / 350–410 |
620–690 / 400–460 |
|
870 |
430–490 / 270–320 |
480–540 / 300–360 |
4. Creep / Stress-Rupture Comparison (Typical Estimates)
|
Condition |
Nimonic 80A (N07080) |
Nimonic 90 (N07090) |
|---|---|---|
|
750°C / 240 MPa (1000h target) |
≈ 150–300 h (marginal) |
≈ 1000–2000 h ✅ |
|
750°C / 180 MPa |
≈ 500–1000 h |
≈ 2000–3000 h+ |
|
815°C / 150 MPa |
≈ 50–150 h |
≈ 500–1000 h ✅ |
|
870°C / 100 MPa |
≈ 80–200 h (not preferred) |
≈ 500–1000 h ✅ |
→ Nimonic 90 shows clearly superior stress-rupture at 750–870°C due to Co-enhanced γ′ stability and slightly higher γ′ volume.
→ Nimonic 80A is acceptable for lower stressed / lower T (≤ 700–730°C design) turbine blades or fasteners where cost/spec legacy favors it.
5. Oxidation & Environmental Resistance
Both form Cr₂O₃ scales (Cr ≈ 19.5%); Nimonic 90's minor Al (1.0–2.0%) can give a trace Al₂O₃ sub-layer → very slightlybetter scale adherence at > 950°C vs. 80A (Al 1.0–1.8% also present in 80A; difference minimal).
Continuous oxidation limit for both ≈ 1040°C (1900°F) in static air.
Sulfidation / hot corrosion: similar (Ni-base, Cr≈20%); Co-free in both → no Co-base sulfide advantage.
6. Weldability & SAC Susceptibility
|
Factor |
Nimonic 80A (N07080) |
Nimonic 90 (N07090) |
|---|---|---|
|
SAC (Strain-Age Cracking) Tendency |
Moderate (Al+Ti≈3.8%; lower Co → γ′ reforms on cooling) |
Moderate–High (higher Al+Ti & Co → stronger γ′ re-precip; similar weld care needed) |
|
Recommended Filler |
Matching N07080 or Inconel 82 (lower strength) |
Matching N07090 or Inconel 82 (lower strength) |
|
Typical Welded Application |
Light repair / attachment; not large welded fabrications |
Same — both unsuited for large thin-wall welded combustor liners (use Nimonic 263) |
|
Post-Weld HT |
Full re-solution + age preferred for critical parts |
Full re-solution + double-age preferred |
→ Neither is a "weld-friendly sheet alloy"; — both are forged/machined part alloys (blades, vanes, springs). Differences in weldability are second-order vs. the creep/strength distinction.
7. Typical Applications by Grade
|
Nimonic 80A (N07080 / 2.4631) |
Nimonic 90 (N07090 / 2.4632) |
|---|---|
|
Turbine blades (early aero engines, industrial < 730°C design metal T) |
Turbine blades (small / legacy engines where 870°C creep needed) |
|
Nozzle guide vanes (lower stressed) |
Nozzle guide vanes (NGVs) — preferred for 750–870°C design |
|
High-temp studs / fasteners (lower stress) |
High-temp studs / fasteners (to 870°C design) |
|
Gas turbine springs (lighter duty) |
High-temp valve springs / lock rings (400–600°C design) — classic Nimonic 90 app. |
|
Often selected for legacy British aero-engine MRO where DWG calls out Nimonic 80A |
Selected when DWG calls out Nimonic 90 or when 750–870°C creep is critical |
8. Selection Decision Guide
Is the design metal temperature > 730–750°C AND stress-rupture @ 750°C > 200 MPa required?
├─ YES → ✅ Specify Nimonic 90 (N07090)
│ Reason: Co ~18% → γ′ solvus ↑ → superior 750–870°C creep/rupture
└─ NO → Is the drawing / legacy spec calling out Nimonic 80A (N07080)?
├─ YES & acceptable life at ≤ 700–730°C → ✅ Nimonic 80A (cost/avail legacy)
├─ YES but needs 750°C+ performance → Upgrade to Nimonic 90 (verify DWG allow)
└─ NO → Re-evaluate: maybe Nimonic 263 (welded sheet), Inconel 718 (disc/bolt ≤650°C),
Hastelloy X (low stress combustor), Haynes 188 (cyclic oxidation >950°C)
9. Summary Comparison Table
|
Feature |
Nimonic 80A (N07080 / 2.4631) |
Nimonic 90 (N07090 / 2.4632) |
|---|---|---|
|
Co content |
≤ 2.0 % (typ ~1.0%) |
15.0–21.0 % (typ 18%) |
|
(Al+Ti) total |
≈ 3.4–4.2 % |
≈ 3.8–4.8 % |
|
γ′ Solvus |
≈ 950–970°C |
≈ 985–1010°C |
|
750°C 1000h Rupture Str. |
~ 180–200 MPa (marginal) |
~ 240 MPa |
|
870°C 1000h Rupture Str. |
~ 70–80 MPa (not preferred) |
~ 100 MPa |
|
Typical Use |
Legacy blade/vane/fastener ≤ 700–730°C |
Blade/vane/spring/fastener 650–870°C (pref. > 730°C) |
|
Welding SAC |
Moderate |
Moderate–High (both need care) |
|
Sheet-Metal Combustor? |
No |
No (use Nimonic 263) |
10. Conclusion
Nimonic 90 (UNS N07090 / W.Nr. 2.4632) is the higher-performance evolution of Nimonic 80A, distinguished primarily by 15–18% Co which raises γ′ solvus and improves creep-rupture strength in the 750–870°C range. It is the preferred choice for modern turbine blades/NGVs and high-temp springs when design temperature exceeds ~730°C or stress-rupture requirements are demanding.
Nimonic 80A (UNS N07080 / W.Nr. 2.4631) remains in use for legacy aero-engine MRO, lower-stressed blades/vaned < 730°C, and fasteners where original drawing specifies it and upgraded performance is not required.
Neither alloy is intended for large welded thin-wall fabrications (that role belongs to Nimonic 263 or Hastelloy X in the Nimonic family context).