Incoloy 825 (UNS N08825 / W.Nr. 2.4858 / GB NS1402) is a titanium-stabilized, nickel-iron-chromium alloy with additions of molybdenum, copper, and a controlled low carbon content. It is not a precipitation-hardenable superalloy. Its corrosion resistance is derived from solid-solution strengthening combined with high nickel content (immunity to chloride-induced stress corrosion cracking), molybdenum (pitting/crevice resistance), and copper (resistance to reducing acids such as sulfuric and phosphoric acid). Titanium stabilization (Ti/C ≥ 8) prevents sensitization and intergranular corrosion after welding without requiring post-weld solution annealing. This guide provides strict, specification-based technical data for design reference and material evaluation.
1. Chemical Composition (wt%, per ASTM B424 / ASME SB424 / NACE MR0175)
|
Element |
Specified Range (wt%) |
Functional Significance |
|---|---|---|
|
Nickel (Ni) |
38.0 – 46.0 (typ. 42.0–44.0) |
Stabilizes austenite; ≥ ~35% Ni gives immunity to chloride stress corrosion cracking (SCC); improves resistance in reducing environments |
|
Chromium (Cr) |
19.5 – 23.5 (typ. 21.0–22.0) |
Provides resistance to oxidizing acids (e.g., nitric acid) and atmospheric oxidation; contributes to pitting resistance |
|
Iron (Fe) |
22.0 min / Balance (typ. 22–26) |
Austenite stabilizer; reduces material cost vs. full Ni-base alloys |
|
Molybdenum (Mo) |
2.5 – 3.5 (typ. 3.0) |
Increases resistance to pitting and crevice corrosion in chloride-containing media; raises PREN |
|
Copper (Cu) |
1.5 – 3.0 (typ. 2.0–2.5) |
Confers tolerance to non-oxidizing acids—especially sulfuric (H₂SO₄) and phosphoric (H₃PO₄) acids at moderate concentrations and temperatures |
|
Titanium (Ti) |
0.6 – 1.2 (typ. 0.85–1.0) |
Ti/C ratio ≥ 8–12; ties up carbon as TiC, preventing Cr₂₃C₆ precipitation at grain boundaries → resists intergranular corrosion after welding |
|
Carbon (C) |
≤ 0.05 (typ. ≤ 0.03) |
Low carbon + Ti stabilization minimizes sensitization risk |
|
Manganese (Mn) |
≤ 1.0 |
Deoxidizer; minimal effect on corrosion if within spec |
|
Silicon (Si) |
≤ 0.5 |
Deoxidizer; kept low to avoid embrittlement |
|
Sulfur (S) |
≤ 0.015 (premium ≤ 0.005) |
Detrimental to hot workability and weldability; strictly controlled |
|
Aluminum (Al) |
≤ 0.2 |
Residual element |
|
Phosphorus (P) |
≤ 0.030 |
Residual impurity |
Pitting Resistance Equivalent Number (PREN):
PREN = %Cr + 3.3 × %Mo + 16 × %N ≈ 32–35 (vs. 316L ≈ 24, 904L ≈ 33–35, 6Mo SS ≈ 40–43, Alloy C-276 ≈ 68+)
2. Physical Constants
|
Property |
Value |
Note |
|---|---|---|
|
Density |
8.14 g/cm³ (0.294 lb/in³) |
— |
|
Melting Range |
1370 – 1400 °C (2498 – 2552 °F) |
Solidus ~1370°C, Liquidus ~1400°C |
|
Specific Heat (20 °C) |
440 J/(kg·K) |
— |
|
Thermal Conductivity |
11.4 W/(m·K) @ 20°C; 14.5 @ 300°C; 19.0 @ 600°C |
Lower than carbon steel; similar to austenitic SS |
|
Coefficient of Thermal Expansion (CTE) |
14.4 × 10⁻⁶ /K (20–600°C mean) |
Intermediate between 300-series SS and high-Ni alloys |
|
Electrical Resistivity (20 °C) |
~1.13 µΩ·m |
— |
|
Magnetic Behavior |
Fully austenitic — non-magnetic in all conditions |
— |
|
Elastic (Young's) Modulus (20 °C) |
193–200 GPa (28–29 ×10³ ksi) |
Decreases with temperature |
3. Mechanical Properties — Solution-Annealed Condition (per ASTM B424 / B423 / B425)
Incoloy 825 is solution-annealed only (typically 980–1040°C, rapid quenched). It is not age-hardenable.
Room-Temperature Minimum Requirements (Plate / Tube / Bar):
|
Property |
ASTM Minimum |
Typical Mill Range |
|---|---|---|
|
Tensile Strength (Rm) |
≥ 586 MPa (85 ksi) |
620 – 750 MPa |
|
Yield Strength (Rp0.2) |
≥ 241 MPa (35 ksi) |
270 – 350 MPa |
|
Elongation (A₅₀ₘₘ or 4D) |
≥ 30 % |
35 – 50 % |
|
Hardness |
≤ 95 HRB (often 70–90 HRB) |
~160–200 HBW |
|
Charpy V-notch Impact (RT) |
Not specified; typically ≥ 100 J |
High toughness even at sub-zero temps |
Representative Elevated-Temperature Values (Solution-Annealed, Typical):
|
Temp (°C) |
Tensile Strength Rm (MPa) |
Yield Strength Rp0.2 (MPa) |
Elongation A₅ (%) |
|---|---|---|---|
|
20 |
620–720 |
270–350 |
35–48 |
|
100 |
590–670 |
240–320 |
35–45 |
|
300 |
530–610 |
210–280 |
33–42 |
|
400 |
500–570 |
195–260 |
32–40 |
|
500 |
470–530 |
180–240 |
30–38 |
|
600 |
420–490 |
165–215 |
28–36 |
|
700 |
360–420 |
140–190 |
28–35 |
Incoloy 825 is not intended for high-load, long-term service > 450–480°C (creep strength is modest). For high-temperature load-bearing, consult Incoloy 800HT, Inconel 600/601, or A-286 / Inconel 718 depending on temperature.
4. Corrosion-Resistance Mechanism Summary
Chloride Stress Corrosion Cracking (SCC): Ni ≥ 42% renders alloy essentially immune to transgranular Cl⁻-SCC that attacks 300-series SS > 60°C.
Pitting / Crevice Corrosion: Mo (~3%) + high Cr → PREN 32–35; suitable for seawater splash/spray zones and desalination equipment (superior to 316L / 2205 in SCC, slightly less pitting-resistant than 6% Mo SS or C-276).
Reducing Acids (H₂SO₄ / H₃PO₄): Cu (1.5–3%) enables service in sulfuric acid up to ~40 wt% at ≤ 60–80°C (dependent on aeration, impurities); also used in wet-process phosphoric acid service containing F⁻ and Cl⁻.
Intergranular Corrosion after Welding: Ti-stabilized, low-carbon design prevents Cr-carbide precipitation at grain boundaries → weld HAZ remains resistant to intergranular attack per ASTM A262 Practice E (Strauss test) or ASTM G28.
Sour Service (Oil & Gas): When supplied in solution-annealed condition with hardness ≤ 35 HRC (typically 70–90 HRB), meets NACE MR0175 / ISO 15156 for H₂S/CO₂/Cl⁻ environments (material must not be cold-worked to > HRC 35).
5. Applicable Standards by Product Form
|
Product Form |
ASTM / ASME Standard |
DIN / EN |
GB (China) |
|---|---|---|---|
|
Plate / Sheet / Strip |
ASTM B424 / ASME SB424 |
DIN 17744 (W.Nr. 2.4858) |
GB/T 15007 (NS1402), GB/T 2054 |
|
Seamless Tube / Pipe |
ASTM B423 / ASME SB423 |
DIN 17751 |
GB/T 21832 (seamless), GB/T 21833 (welded) |
|
Welded Pipe |
ASTM B704 / ASME SB704 |
— |
GB/T 21833 |
|
Round Bar / Forging Stock |
ASTM B425 / ASME SB425; ASTM B564 (forgings) |
DIN 17752 / DIN 17754 |
GB/T 15008, NB/T 47010 |
|
Welding Consumables |
AWS A5.14 ERNiFeCr-1 or ERNiCrMo-3 (Inconel 112/82 also used as over-alloyed fillers) |
— |
GB/T 15620 |
6. Summary & Engineering Note
Incoloy 825 (UNS N08825 / W.Nr. 2.4858) is a titanium-stabilized Ni-Fe-Cr-Mo-Cu solid-solution alloy offering:
Immunity to chloride-induced SCC (Ni ≥ 42%)
Resistance to sulfuric / phosphoric acids (Cu addition)
Resistance to seawater pitting/crevice corrosion (PREN 32–35, Mo addition)
Intergranular corrosion resistance in welded condition (Ti-stabilized, low C)
Good fabricability and weldability with conventional processes
It is the preferred cost-effective step-up from 316L / 904L in sour, acidic, or chloride-rich environments, and a more economically viable option than Hastelloy C-276 or Inconel 625 where ultimate resistance to strong halide + strong reducing acids is not required.
For qualified material test reports (EN 10204 3.1), stock availability of plate / bar / seamless tube, or corrosion-appraisal consultation on Incoloy 825 (UNS N08825), please contact your technical representative.