Hastelloy B3 and Hastelloy C276 are both high-performance nickel-based alloys developed by Haynes International. While they share a similar family name and are designed to withstand highly corrosive environments, they differ in chemical composition, corrosion resistance, and ideal applications. Understanding the distinctions between Hastelloy B3 vs C276 helps engineers and buyers choose the right alloy for specific chemical processing and industrial environments.

The most notable difference between Hastelloy B3 and C276 lies in their chemical makeup. Hastelloy B3 is a nickel-molybdenum alloy with a high molybdenum content (around 28–30%) and very low chromium levels. This composition provides excellent resistance to hydrochloric acid and other strongly reducing agents. In contrast, Hastelloy C276 contains a balanced mixture of nickel, molybdenum, and chromium (typically 15.5% Mo and 16% Cr), offering superior resistance to both oxidizing and reducing media.
Hastelloy B3 performs exceptionally well in pure hydrochloric acid and similar reducing environments, resisting pitting, stress-corrosion cracking, and knife-line attack. However, it is less suitable for oxidizing environments because the lack of chromium reduces its protective oxide film stability.
Hastelloy C276, on the other hand, provides universal corrosion resistance. It withstands oxidizing agents such as ferric and cupric chlorides, hot contaminated media, chlorine gas, and hypochlorite. Its versatility makes it one of the most corrosion-resistant alloys available for chemical processing, pollution control, and waste treatment applications.
Both alloys maintain high mechanical strength and stability across a wide temperature range, but C276 generally shows better oxidation resistance at elevated temperatures due to its chromium content. Hastelloy B3 offers good thermal stability up to about 1000°C, but prolonged exposure to oxidizing conditions at high temperatures may cause surface degradation.
Both Hastelloy B3 and C276 exhibit good workability and weldability, though care must be taken to avoid contamination during welding. Hastelloy B3 offers improved thermal stability and processing characteristics compared to its predecessor B2, which reduces the risk of grain boundary carbide precipitation. Hastelloy C276 is more forgiving during welding operations and can be fabricated into complex components such as vessels, tubing, and reactors with fewer post-weld heat treatments.
Hastelloy B3 is used primarily in environments where hydrochloric acid and other strong reducing acids are present. Typical applications include acid production plants, chemical reactors, heat exchangers, and evaporators.
Hastelloy C276 is widely used in industries where mixed or unpredictable chemical conditions exist. It is a common choice for chemical processing equipment, flue gas scrubbers, pulp and paper bleaching systems, and pollution control units.
| Property | Hastelloy B3 | Hastelloy C276 |
|---|---|---|
| Primary Alloying Elements | Nickel, Molybdenum | Nickel, Molybdenum, Chromium |
| Corrosion Resistance | Excellent in reducing environments | Excellent in both oxidizing and reducing environments |
| Best Resistance To | Hydrochloric acid, Hydrogen chloride | Chlorine gas, Ferric chloride, Hot contaminated acids |
| Oxidation Resistance | Moderate | High |
| Weldability | Good, improved over B2 | Excellent |
| Applications | Acid production, Reactors | Chemical plants, Pollution control |
In summary, Hastelloy B3 is ideal for pure reducing acid environments, especially hydrochloric acid, while Hastelloy C276 is the preferred choice when versatility and resistance to both oxidizing and reducing agents are required. Selecting between B3 and C276 depends on the specific chemical conditions, temperature, and process environment involved.